AN OPEN-FRAMEWORK ZINC PHOSPHATE WITH ZN-O-ZN LINKAGES

被引：74

作者：

SONG, TY

HURSTHOUSE, MB

CHEN, JH

XU, JN

MALIK, KMA

JONES, RH

XU, RR

THOMAS, JM

机构：

[1] UCL ROYAL INST GREAT BRITAIN, DAVY FARADAY RES LAB, 21 ALBEMARLE ST, LONDON W1X 4BS, ENGLAND

[2] JILIN UNIV, DEPT CHEM, CHANGCHUN, PEOPLES R CHINA

[3] UNIV WALES COLL CARDIFF, SCH CHEM & APPL CHEM, CARDIFF CF1 3TB, WALES

[4] UNIV KEELE, DEPT CHEM, KEELE ST5 5BG, STAFFS, ENGLAND

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 09期

关键词：

Amines - Crystallization - Ethylene - Glycols - Molecular structure - Phosphates - Porous materials - Zinc oxide;

D O I：

10.1002/adma.19940060914

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Open framework crystalline solids have great potential as catalysts and absorbers and for many other applications in materials science. The synthesis and structural characterization of a new zinc phosphate prepared from a predominantly non-aqueous system are described. The unique features of the compound, which has the empirical formula Zn4(PO4)3(H2O)(C2H5NH3), such as three-coordinated oxygen atoms and a ratio of Zn to P greater than 1, are discussed.

引用

页码：679 / 680

页数：2

共 18 条

[11] NANOCHEMISTRY - SYNTHESIS IN DIMINISHING DIMENSIONS [J].