ORGANIC ADDITIVE-MEDIATED SYNTHESIS OF NOVEL COBALT(II) HYDROXIDES

被引：51

作者：

ISMAIL, J

AHMED, MF

KAMATH, PV

SUBBANNA, GN

UMA, S

GOPALAKRISHNAN, J

机构：

[1] INDIAN INST SCI,MAT RES CTR,BANGALORE 560012,KARNATAKA,INDIA

[2] UNIV AGR SCI,CENT COLL,DEPT CHEM,BANGALORE 560001,KARNATAKA,INDIA

[3] INDIAN INST SCI,SOLID STATE & STRUCT CHEM UNIT,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1995年 / 114卷 / 02期

关键词：

D O I：

10.1006/jssc.1995.1084

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical precipitation of cobalt(II) hydroxide from nitrate solutions containing organic molecules, such as glucose, fructose, lactose, glycerol, and citric acid, yields a new modification of cobalt (II) hydroxide (a = 3.09 +/- 0.03 Angstrom, c = 23.34 +/- 0.36 Angstrom) that is isostructural with cu-nickel hydroxide; precipitation in the absence of organic additives gives the stable, brucite-like, beta-CO (OH)(2). (C) 1995 Academic Press, Inc.

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页码：550 / 555

页数：6

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