DETERMINATION OF COPPER IN SEAWATER BY ADSORPTIVE VOLTAMMETRY WITH 1,2-DIHYDROXYANTHRAQUINONE-3-SULFONIC ACID

被引：14

作者：

QUENTEL, F

ELLEOUET, C

MADEC, C

机构：

[1] URA CNRS 322, Université de Bretagne Occidentale, Laboratoire de Chimie Analytique, Brest, 29275, 6

来源：

ELECTROANALYSIS | 1994年 / 6卷 / 08期

关键词：

COPPER; ADSORPTIVE STRIPPING VOLTAMMETRY; 1,2-DIHYDROXYANTHRAQUINONE-3-SULFONIC ACID;

D O I：

10.1002/elan.1140060812

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method is described for the determination of copper in seawater by adsorptive stripping voltammetry after accumulation of a 1,2-dihydroxyanthraquinone-3-sulfonic acid (DASA) comples. The effects of various operational parameters (pH, ligand concentration, potential, and accumulation time) on the reduction current of the adsorbed chelate are discussed. A linear current concentration relationship was observed up to 5 x 10(-8) M. The detection limit is 0.3 nM.

引用

页码：683 / 688

页数：6