EFFECTS OF MONOSUBSTITUTED PHENOL ADDITIVES ON THE ELECTRICAL AND MECHANICAL-PROPERTIES OF ELECTROCHEMICALLY SYNTHESIZED POLYPYRROLE

被引：16

作者：

FUKUYAMA, M

NANAI, N

KOJIMA, T

KUDOH, Y

YOSHIMURA, S

机构：

[1] Matsushita Research Institute Tokyo, Inc., Tama-ku, Kawasaki, 214

来源：

SYNTHETIC METALS | 1993年 / 58卷 / 03期

关键词：

D O I：

10.1016/0379-6779(93)91145-R

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Polypyrrole (PPy) which is electrochemically synthesized with a mono-substituted phenol additive has enhanced conductivity, thermal stability and tensile strength. From elemental analysis data, mass spectra and FT-IR spectra, there is no obvious evidence that the additive is incorporated in PPy. Electronic absorption spectra and laser Raman spectra show that the additive reduces the polaron peak and enhances the bipolaron peak. The increased structural regularity is considered to be the reason for the improvement of the electrical and mechanical properties.

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页码：367 / 371

页数：5

相关论文

共 18 条

[1] CONDUCTING POLYMER GAS SENSORS .1. FABRICATION AND CHARACTERIZATION [J].

BARTLETT, PN ;

ARCHER, PBM ;

LINGCHUNG, SK .

SENSORS AND ACTUATORS, 1989, 19 (02) :125-140

[2] STUDY ON POLYPYRROLE FILM BY ELECTROCHEMICAL POLYMERIZATION IN AQUEOUS-SOLUTION [J].

DONG, SJ ;

DING, J .

SYNTHETIC METALS, 1987, 20 (01) :119-124

[3]

FUKUYAMA M, IN PRESS MOL CRYST L

[4] RAMAN-SPECTRA OF POLYPYRROLE AND ITS 2,5-C-13-SUBSTITUTED AND C-DEUTERATED ANALOGS IN DOPED AND UNDOPED STATES [J].

FURUKAWA, Y ;

TAZAWA, S ;

FUJII, Y ;

HARADA, I .

SYNTHETIC METALS, 1988, 24 (04) :329-341

[5] ENHANCEMENT OF THE ELECTRICAL-CONDUCTIVITY OF POLYPYRROLE FILM BY STRETCHING - INFLUENCE OF THE POLYMERIZATION CONDITIONS [J].

HAGIWARA, T ;

HIRASAKA, M ;

SATO, K ;

YAMAURA, M .

SYNTHETIC METALS, 1990, 36 (02) :241-252

[6] EVOLUTION OF POLARON STATES INTO BIPOLARONS IN POLYPYRROLE [J].

KAUFMAN, JH ;

COLANERI, N ;

SCOTT, JC ;

KANAZAWA, KK ;

STREET, GB .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 118 (1-4) :171-177

[7] MORPHOLOGY AND ELECTROCHEMICAL PROPERTIES OF POLYPYRROLE FILMS PREPARED IN AQUEOUS AND NONAQUEOUS SOLVENTS [J].

KO, JM ;

RHEE, HW ;

PARK, SM ;

KIM, CY .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (03) :905-909

[8]

KOEZUKA H, 1989, SYNTHETIC MET, V28, pC753, DOI 10.1016/0379-6779(89)90600-0

[9] AN ALUMINUM SOLID ELECTROLYTIC CAPACITOR WITH AN ELECTROCONDUCTING-POLYMER ELECTROLYTE [J].

KUDOH, Y ;

TSUCHIYA, S ;

KOJIMA, T ;

FUKUYAMA, M ;

YOSHIMURA, S .

SYNTHETIC METALS, 1991, 41 (03) :1133-1136

[10] ELECTRICAL-CONDUCTIVITY OF POLYPYRROLE FILMS DOPED WITH CARBOXYLATE ANIONS [J].

KUWABATA, S ;

NAKAMURA, J ;

YONEYAMA, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (06) :1788-1792