ASYMMETRIC-SYNTHESIS OF FUNCTIONALIZED NITROCOMPOUNDS THROUGH MICHAEL ADDITION OF FORMALDEHYDE SAMP HYDRAZONE TO NITROOLEFINS

被引：25

作者：

FERNANDEZ, R

GASCH, C

LASSALETTA, JM

LLERA, JM

机构：

[1] UNIV SEVILLA,DEPT QUIM ORGAN,E-41071 SEVILLE,SPAIN

[2] UNIV SEVILLA,FAC FARM,DEPT QUIM ORGAN & FARMACEUT,E-41071 SEVILLE,SPAIN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 03期

关键词：

FORMALDEHYDE SAMP HYDRAZONE; NITROOLEFINS; CHIRAL BETA-NITROHYDRAZONES;

D O I：

10.1016/0040-4039(94)85083-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral beta-nitrohydrazones 7 can be easily prepared in goad yields and diastereoselectivities by non catalyzed Michael addition of formaldehyde SAMP hydrazone 6 to simple nitroolefins.

引用

页码：471 / 472

页数：2

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