RYDBERG STATES OF GAS-PHASE CHLOROBENZENE OBSERVED BY DOUBLE-RESONANCE MULTIPHOTON IONIZATION PHOTOELECTRON-SPECTROSCOPY

被引：10

作者：

ASSELIN, P

PIUZZI, F

LECALVE, J

MONS, M

DIMICOLI, I

机构：

[1] Service des Photons, Atomes et Molécules, CEA, Centre d'Etudes de Saclay, Cedex, Bâtiment 522

来源：

CHEMICAL PHYSICS | 1994年 / 181卷 / 1-2期

关键词：

D O I：

10.1016/0301-0104(94)85029-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this first application of double resonance multiphoton ionization photoelectron spectroscopy to study the higher excited states of a polyatomic molecule, we have obtained the double resonance absorption spectrum of chlorobenzene in the energy region 56000 to 66700 cm-1. Three new band systems are identified as members of Rydberg series converging to the first ionization energy. These systems with the 0(0)0 bands at 63000, 64690 and 66390 cm-1 are tentatively assigned to the 3d, 4p and 4d Rydberg states, respectively.

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页码：271 / 279

页数：9

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