SOLVENT EFFECT ON ENANTIOSELECTIVE HYDROGENATION OF (E)-ALPHA-PHENYLCINNAMIC ACID WITH CINCHONIDINE-MODIFIED PALLADIUM CATALYSTS

被引：38

作者：

NITTA, Y

KOBIRO, K

机构：

来源：

CHEMISTRY LETTERS | 1995年 / 02期

关键词：

D O I：

10.1246/cl.1995.165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of a solvent with larger dielectric constant results in higher enantioselectivity in the hydrogenation of (E)-alpha-phenylcinnamic acid with a cinchonidine-modified Pd catalyst. The reaction in N,N-dimethylformamide containing 10vol% of water with a 5wt% Pd/TiO2 catalyst leads to an optical yield of 53% of S-(+)-2,3-diphenylpropionic acid.

引用

页码：165 / 165

页数：1

共 6 条

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