AZA-DIHYDRO[60]FULLERENE IN THE GAS-PHASE - A MASS-SPECTROMETRIC AND QUANTUMCHEMICAL STUDY

被引：82

作者：

AVERDUNG, J ^{[1
]}

LUFTMANN, H ^{[1
]}

SCHLACHTER, I ^{[1
]}

MATTAY, J ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,D-48149 MUNSTER,GERMANY

来源：

TETRAHEDRON | 1995年 / 51卷 / 25期

关键词：

60]FULLERENE; 1,2-AZIRINO-[60]FULLERENE; AZA-HETEROFULLERENE; AMI AND AMBER CALCULATIONS;

D O I：

10.1016/0040-4020(95)00361-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new approach to produce heterofullerenes is described. Starting from a fullerene with an intact cage which is activated by suitable exohedral functionalization, the first aza-heterofullerene is generated in the gas phase under DCl mass-spectrometric conditions. On the basis of AMl-calculations the 1,2-closed structure is proposed to be the most stable one.

引用

收藏

页码：6977 / 6982

页数：6

相关论文

共 25 条

[1] SYNTHESIS OF 1,2-(2,3-DIHYDRO-1H-AZIRINO)-[60]FULLERENE, THE PARENT FULLEROAZIRIDINE [J].

AVERDUNG, J ;

LUFTMANN, H ;

MATTAY, J ;

CLAUS, KU ;

ABRAHAM, W .

TETRAHEDRON LETTERS, 1995, 36 (17) :2957-2958

[2] FULLERENES WITH METALS INSIDE [J].

CHAI, Y ;

GUO, T ;

JIN, CM ;

HAUFLER, RE ;

CHIBANTE, LPF ;

FURE, J ;

WANG, LH ;

ALFORD, JM ;

SMALLEY, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) :7564-7568

[3] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[4] C-60 - FROM SOOT TO SUPERCONDUCTORS [J].

DIEDERICH, F ;

WHETTEN, RL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (06) :678-680

[5]

DIEDERICH F, 1991, ANGEW CHEM, V103, P695

[6] DOPING BUCKY - FORMATION AND PROPERTIES OF BORON-DOPED BUCKMINSTERFULLERENE [J].

GUO, T ;

JIN, CM ;

SMALLEY, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (13) :4948-4950

[7]

HADDON RC, 1994, RECENT ADV CHEM PHYS, P2

[8]

Hirsch A, 1994, CHEM FULLERENES, DOI DOI 10.1002/9783527619214

[9] HETEROFULLERENES - STRUCTURE AND PROPERTY PREDICTIONS, POSSIBLE USES AND SYNTHESIS PROPOSALS [J].

KARFUNKEL, HR ;

DRESSLER, T ;

HIRSCH, A .

JOURNAL OF COMPUTER-AIDED MOLECULAR DESIGN, 1992, 6 (05) :521-535

[10] SOLID C-60 - A NEW FORM OF CARBON [J].

KRATSCHMER, W ;

LAMB, LD ;

FOSTIROPOULOS, K ;

HUFFMAN, DR .

NATURE, 1990, 347 (6291) :354-358