1ST SYNTHESIS OF SULFINYL SUBSTITUTED TRICARBONYL(ETA(6)-ARENE)CHROMIUM(0) COMPLEXES

被引：19

作者：

PEREZENCABO, A

PERRIO, S

SLAWIN, AMZ

THOMAS, SE

WIERZCHLEYSKI, AT

WILLIAMS, DJ

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期

关键词：

D O I：

10.1039/c39930001059

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimethyldioxirane efficiently oxidises tricarbonylchromium(0) complexes of sulfenyl substituted arenes to tricarbonylchromium(0) complexes of sulfinyl substituted arenes: ortho substituted complexes are oxidised with high diastereoselectivity and determination of the relative stereochemistry of the oxidation products by inter alia an X-ray crystal structure analysis of tricarbonyl[eta6-1-(tert-butylsulfinyl)-2-methoxybenzene]chromium(0) (2b(x)) revealed that oxidations of methylsulfenyl and tert-butylsulfenyl substituted complexes proceed to give complementary diastereoisomers.

引用

页码：1059 / 1062

页数：4

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