DIASTEREOSELECTIVE REDUCTIONS OF CYCLOHEXANONES WITH DIISOBUTYLALUMINUM 2,6-DI-TERT-BUTYL-4-METHYLPHENOXIDE

被引：5

作者：

HAUBENSTOCK, H

机构：

[1] Chemistry Department, The City University, New York The College of Staten Island

来源：

TETRAHEDRON | 1990年 / 46卷 / 19期

关键词：

D O I：

10.1016/S0040-4020(01)87854-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Isomerization of aluminum alcoholates occurs in the reduction of cyclohexanones with diisobutylaluminum 2,6-di-t-butyl-4-methylphenoxide 1 in the presence of excess ketone. Factors affecting the diastereoselectivity of reduction of cyclohexanones with I were investigated. © 1990.

引用

页码：6633 / 6636

页数：4

共 6 条

[1]

BARTMANN W, 1987, LIEBIGS ANN CHEM, P321

[2] LITHIUM TRI-SEC-BUTYLBOROHYDRIDE - NEW REAGENT FOR REDUCTION OF CYCLIC AND BICYCLIC KETONES WITH SUPER STEREOSELECTIVITY - REMARKABLY SIMPLE AND PRACTICAL PROCEDURE FOR CONVERSION OF KETONES TO ALCOHOLS IN EXCEPTIONALLY HIGH STEREOCHEMICAL PURITY [J].