AN N-15 NMR SPECTROSCOPIC STUDY OF SOME RHODIUM COMPLEXES OF 3,5-DICARBOMETHOXY-4-PHENYLPYRIDINE-N-15

被引：17

作者：

CARLTON, L

DESOUSA, G

机构：

[1] Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, Johannesburg

来源：

POLYHEDRON | 1993年 / 12卷 / 11期

关键词：

D O I：

10.1016/S0277-5387(00)84329-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N-15 NMR data are reported for the complexes [cis-RhX(PPh3)2(dcpp-N-15)], [Rh(H)2X(PPh3)2(dCPP-N-15)] (X = Cl, SC6F5; dcpp-N-15 = 3,5-dicarbomethoxy-4-phenylpyridine-N-15), [RhCl(PPh3)(L)(dcpp-N-15)] (L = C2H4, CO) and [Rh(H)(C2Ph)(X) (PPh3)2(dcpp-N-15)] (X = Cl, OCN, N3, C2Ph), prepared in situ from [RhX(PPh3)3], [Rh2Cl2(C2H4)4] and [Rh2(SC6F5)2(PPh3)4].

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页码：1377 / 1382

页数：6

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