ORGANOMETALLIC IMIDO COMPLEXES HIGHERVALENT DERIVATIVES OF THE D-METAL ADIDS .2. ALKYLPENTADIENYL, ARYLPENTADIENYL, AND CYCLOPENTADIENYL-SUBSTITUTED MOLYBDENUM(VI) AND TUNGSTEN(VI) IMIDO COMPLEXES

被引：31

作者：

RADIUS, U ^{[1
]}

SUNDERMEYER, J ^{[1
]}

机构：

[1] UNIV WURZBURG,INST ANORGAN CHEM,HUBLAND,W-8700 WURZBURG,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 10期

关键词：

IMIDO COMPLEXES; MOLYBDENUM COMPLEXES; TUNGSTEN COMPLEXES;

D O I：

10.1002/cber.19921251004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CpMo(NtBu)2Cl (1a) and CpW(NtBU)2Cl (1b) (Cp = eta5-C5H5) react with organolithium reagents to form alkyl and aryl complexes of the type CpMo(NtBU)2R 2a - 4a and CpW(NtBu)2R 2b - 4b, resp., (R = Me, CH2SiMe3, Ph), highly volatile organometallic compounds, which were isolated as analytically and spectroscopically pure oils by vacuum destillation. On the other hand, the protolysis reaction of la and lb with excess of HCl gas affords monoimido complexes CpMo(NtBu)Cl3 (5a) and CpW(NtBu)Cl3 (5b), respectively.

引用

页码：2183 / 2186

页数：4

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