REACTIVITY OF ISOTHIOCYANATES OF 2-F-ALKYLETHYL AND THEIR ISOMERS WITH STABILIZED PHOSPHONIUM YLIDES

被引：5

作者：

BOLLENS, E ^{[1
]}

SZONYI, F ^{[1
]}

TRABELSI, H ^{[1
]}

CAMBON, A ^{[1
]}

机构：

[1] UNIV NICE SOPHIA ANTIPOLIS,CHIM ORGAN FLUOR LAB,PARC VALROSE,BP 71,F-06018 NICE 2,FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1994年 / 67卷 / 02期

关键词：

D O I：

10.1016/0022-1139(93)02950-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This work reports on the reactivity of 2-F-alkylethyl thiocyanates and isothiocyanates towards stabilized phosphonium ylides. The results led to a new method being devised which allowed the introduction of a perfluoroalkyl chain into the structure of a stabilized phosphonium ylide. The method has been extended with thiocyanates to allow the introduction of an alkyl or alkylaryl chain into such a structure.

引用

页码：177 / 181

页数：5

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