SYNTHESIS, CHARACTERIZATION, AND PROPERTIES OF ETHYLENE-COORDINATED COMPLEXES OF BETA-PLATINUM(II) KETONES

被引：27

作者：

IKURA, K ^{[1
]}

RYU, I ^{[1
]}

OGAWA, A ^{[1
]}

SONODA, N ^{[1
]}

HARADA, S ^{[1
]}

KASAI, N ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 03期

关键词：

D O I：

10.1021/om00049a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of siloxycyclopropanes 1a,b with Zeise's dimer ([Pt(C2H4)Cl2]2) in CHCl3 yields ethylene-coordinated beta-platinum ketones 2a,b in high yields, respectively. The structure of 2b has been determined by X-ray diffraction methods, showing a chloride-bridged dimeric structure. Treatment of 2a with carbon monoxide gives the monomeric CO complex 3a, which has intramolecular coordination of the carbonyl group.

引用

页码：528 / 529

页数：2

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