N,N-DIALKYLCARBAMATO OLIGONUCLEAR COMPLEXES OF IRON(II), INCLUDING [(FE-4(MU(4)-O)(O2CNPR2I)(6))(2)], THE FIRST CRYSTALLOGRAPHICALLY ESTABLISHED UNCHARGED MU-OXO COMPLEX OF IRON(II)

被引：26

作者：

DELLAMICO, DB

CALDERAZZO, F

LABELLA, L

MAICHLEMOSSMER, C

STRAHLE, J

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 13期

关键词：

D O I：

10.1039/c39940001555

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The FeCl2-R(2)NH-CO2 synthetic route yielded N,N-dialkylcarbamato complexes of iron(II), [{Fe(O(2)CNR(2))(2)}(m)] (m = 6, R = Et); controlled hydrolysis of the isopropyl derivative under an inert atmosphere led to the title compound, the first member of the crystallographically new class of uncharged iron(a) complexes containing the bridging oxide ligand.

引用

页码：1555 / 1556

页数：2

共 25 条

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