PROTONATED AMINE TRANSPORT AND CHIRAL RECOGNITION BY 1,2,4-TRIAZOLE ODANDS AND MACROCYCLES

被引：12

作者：

ECHEGOYEN, L

MARTINEZDIAZ, MV

DEMENDOZA, J

TORRES, T

VICENTEARANA, MJ

机构：

[1] UNIV AUTONOMA MADRID,DEPT QUIM,CANTOBLANCO,E-28049 MADRID,SPAIN

[2] UNIV MIAMI,DEPT CHEM,CORAL GABLES,FL 33124

来源：

TETRAHEDRON | 1992年 / 48卷 / 43期

关键词：

D O I：

10.1016/S0040-4020(01)88322-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Transport of ammonium salts across a bulk liquid membrane with chiral macrocycles and podands containing a 1,2,4-triazole subunit takes place with moderate enantioselectivity. Good transport rates were found for both podands and macrocycles, but chiral recognition was less effective with podands.

引用

收藏

页码：9545 / 9552

页数：8

相关论文

共 29 条

[11] HOST-GUEST COMPLEXATION 11 SURVEY OF CHIRAL RECOGNITION OF AMINE AND AMINO ESTER SALTS BY DILOCULAR BISDINAPHTHYL HOSTS [J].

KYBA, EP ;

TIMKO, JM ;

KAPLAN, LJ ;

DEJONG, F ;

GOKEL, GW ;

CRAM, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (14) :4555-4568

[12] MECHANISMS OF BIOLOGICAL ION-TRANSPORT - CARRIERS, CHANNELS, AND PUMPS IN ARTIFICIAL LIPID-MEMBRANES [J].

LAUGER, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1985, 24 (11) :905-923

[13] ENANTIOMERIC RECOGNITION OF ORGANIC AMMONIUM-SALTS BY CHIRAL DIALKYL-SUBSTITUTED TRIAZOLE-18-CROWN-6 LIGANDS [J].

LI, Y ;

ECHEGOYEN, L ;

MARTINEZDIAZ, MV ;

DEMENDOZA, J ;

TORRES, T .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (13) :4193-4196

[14]

LINDENBAUM S, 1979, PROGR MACROCYCL CHEM, V1, P220

[15] NEW CHIRAL HOST MOLECULES DERIVED FROM NATURALLY-OCCURRING MONENSIN IONOPHORE [J].

MARUYAMA, K ;

SOHMIYA, H ;

TSUKUBE, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (13) :864-865

[16] SYNTHESIS AND PROPERTIES OF CHIRAL MACROBICYCLIC AND MACROTRICYCLIC CRYPTANDS CONTAINING THE TRANS-TETRAHYDROFURAN-2,5-DIYLBIS(METHYLENE) SUBUNIT AS THE CHIRAL CENTER [J].

NAEMURA, K ;

KANDA, Y ;

IWASAKA, H ;

CHIKAMATSU, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (05) :1789-1792

[17] ENZYMATIC-HYDROLYSIS OF 2,6-DIACETOXYBICYCLO[3.3.1]NONANE AND 2,6-DIACETOXY-3,3,7,7-TETRAMETHYLBICYCLO[3.3.1]NONANE - A FACILE SYNTHESIS OF THE OPTICALLY-ACTIVE CHIRAL SUBUNIT FOR CROWN ETHERS [J].

NAEMURA, K ;

MATSUMURA, T ;

KOMATSU, M ;

HIROSE, Y ;

CHIKAMATSU, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (03) :239-241

[18] SYNTHESIS OF NOVEL CROWN ETHER INCORPORATING THE (-)-(5S,6R,13S,14R)-5,6,13,14-TETRAHYDRO-5,13-METHANOCYCLOOCTA[1,2-A-5,6-A']- DINAPHTHALENE-6, 14-DIOL SUBUNIT AS THE C2-SYMMETRIC CHIRAL CENTER [J].

NAEMURA, K ;

FUKUNAGA, R .

CHEMISTRY LETTERS, 1985, (11) :1651-1654

[19] SYNTHESIS AND ENANTIOMER RECOGNITION OF CROWN ETHERS CONTAINING THE CIS-4B,5,6,10B,11,12-HEXAHYDROCHRYSENE AND THE CIS-4B,5,9B,10-TETRAHYDROINDENO[2,1-A]-INDENE SUBUNIT AS THE CHIRAL CENTER [J].

NAEMURA, K ;

KOMATSU, M ;

ADACHI, K ;

CHIKAMATSU, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (22) :1675-1676

[20] SYNTHESIS OF CHIRAL CROWN ETHERS DERIVED FROM TRANS, TRANS AND CIS, TRANS-2,2'-SPIROBIINDAN-1,1'-DIOLS - THEIR CHIRAL RECOGNITION AND COMPLEXATION PROPERTIES [J].

NAEMURA, K ;

EBASHI, I ;

NAKAZAKI, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (02) :767-768