THE PHOTO-FENTON REACTION - AN EFFECTIVE PHOTOCHEMICAL WASTE-WATER TREATMENT PROCESS

被引:313
作者
RUPPERT, G [1 ]
BAUER, R [1 ]
HEISLER, G [1 ]
机构
[1] AUSTRIAN ENERGY & ENVIRONM,A-1210 VIENNA,AUSTRIA
关键词
D O I
10.1016/1010-6030(93)80035-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel photochemical degradation method for organic contaminants, the photo-Fenton reaction, has been investigated. Irradiation of an aqueous solution of 4-chlorophenol (4-CP) with light of greater than 320 nm in the presence of H2O2 and Fe2+ accelerates the degradation rate of 4-CP and total organic carbon (TOC) significantly compared with the Fe2+-H2O2 reaction in the dark. The effects of the initial 4-CP and H2O2 concentrations and the intensity of light irradiation on the degradation rates of TOC and H2O2 and the ratio of Fe2+ to Fe3+ are described. Results are compared with the dark Fenton reaction.
引用
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页码:75 / 78
页数:4
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