THE ELECTROCHEMICAL-BEHAVIOR OF SOME POLYVALENT ELEMENTS IN A SODA LIME SILICA GLASS MELT

被引：60

作者：

RUSSEL, C

机构：

[1] Universität Erlangen-Nürnberg, Institut für Werkstoffwissenschaften III (Glas und Keramik), Erlangen

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1990年 / 119卷 / 03期

关键词：

Glass;

D O I：

10.1016/0022-3093(90)90303-4

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The electrochemical behavior of Bi2O3, CeO2, CoO, Cr2O3, SnO2, UO3, and Ta2O5-doped soda-lime-silica glass melts is investigated. The standard potentials are measured in a wide temperature range by the aid of square-wave voltammetry, a fast voltammetric pulse method. From these data, the thermodynamic properties, δH0 and δS0, of the redox reaction: Mex + n + n 2O2 → Mex + n 4O2 were calculated and compared with data in the literature obtained by other, i.e. non-electrochemical, methods. © 1990.

引用

页码：303 / 309

页数：7