TOTAL SYNTHESIS OF (+)-DIHYDROCOMPACTIN

被引：12

作者：

HAGIWARA, H

KONNO, M

NAKANO, T

UDA, H

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 17期

关键词：

D O I：

10.1039/p19940002417

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of (+)-dihydrocompactin 1 has been achieved by employing double Michael reaction of 3-(tert-butyldimethylsiloxy)-1-acetylcyclohexene 13 with methyl crotonate and the TiCl4-promoted aldol condensation of the bis(trimethylsilyl enol ether) of methyl acetoacetate 7 as key reactions.

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页码：2417 / 2430

页数：14

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