PREPARATION OF ORGANO PALLADIUM SOLS FROM PALLADIUM COMPLEXES IN VARIOUS ALCOHOLS

被引：29

作者：

ESUMI, K

ITAKURA, T

TORIGOE, K

机构：

[1] Department of Applied Chemistry, Institute of Colloid and Interface Science, Science University of Tokyo, Shinjuku-ku, Tokyo, 162, Kagurazaka

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1994年 / 82卷 / 01期

关键词：

ALCOHOL; PALLADIUM COMPLEX; PALLADIUM PARTICLES; POLYVINYLPYRROLIDONE;

D O I：

10.1016/0927-7757(93)02619-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Organo palladium sols were prepared from palladium complexes in various alcohols in the presence of polyvinylpyrrolidone. Uniform palladium particles ranging in size between 2 and 4 nm were obtained in 1-pentanol, alpha-phenylethyl alcohol, and beta-phenylethyl alcohol solutions of palladium acetate. In contrast, Pd(acac)2 (acac, 2.4-pentanedionato) yielded particles of wider size distribution compared to those from palladium acetate.

引用

页码：111 / 113

页数：3

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