CALCULATION OF THE POLAR MEDIA REORGANIZATION ENERGY FOR THE MODEL OF 2 DIELECTRIC SPHERES

被引：7

作者：

GERMAN, ED ^{[1
]}

KHARKATS, YI ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,AN FRUMKIN ELECTROCHEM INST,MOSCOW 117071,RUSSIA

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 246卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(95)01129-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of medium dielectric inhomogeneity on the solvent reorganization energy in charge transfer processes is investigated for the model describing reactants as two dielectric spheres. It is shown that this effect is of the order of 16% for the contact position of the reactants and decreases when the inter-reactant distance increases.

引用

页码：427 / 430

页数：4

共 23 条

[1]

BRUSCHWIG CS, 1986, J PHYS CHEM-US, V90, P3657

[2]

Cannon R. D., 1980, ELECTRON TRANSFER RE

[3]

DOGONADZE RR, 1973, ITOGI NAUKI FIZ KHIM, V2

[4] INTRA-MOLECULAR INTERVALENCE CHARGE-TRANSFER IN BIMOLECULAR MIXED-VALENCE COMPLEXES OF METALS [J].

GERMAN, ED .

CHEMICAL PHYSICS LETTERS, 1979, 64 (02) :295-298

[5] OUTER SPHERE ENERGY OF REORGANIZATION IN CHARGE-TRANSFER PROCESSES [J].

GERMAN, ED ;

KUZNETSOV, AM .

ELECTROCHIMICA ACTA, 1981, 26 (11) :1595-1608

[6]

GERMAN ED, 1979, CHEM PHYS LETT, V64, P607

[7]

GERMAN ED, 1988, KHIM FIZ, V7, P305

[8]

GERMAN ED, 1985, IZV AKAD NAUK SSSR, V3, P613

[9]

KHARKATS YI, 1976, ELEKTROKHIMIYA, V12, P592

[10]

KHARKATS YI, 1984, ELEKTROKHIMIYA, V20, P892

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