PHOTOLYTIC AND THERMAL-REACTIONS OF MU-3-AS[WCP(CO)2]3 WITH FE(CO)5 AND FE2(CO)9 - X-RAY STRUCTURE ANALYSES OF THE CLUSTERS FEW2CP2(CO)7[MU-3-AS-WCP(CO)3], FE2WCP(CO)8H[MU-3-AS-WCP(CO)3], AND FE2WCP(CO)8H[MU-3-AS-FECP(CO)2]

被引：10

作者：

CABALLERO, C ^{[1
]}

LEHNE, D ^{[1
]}

NUBER, B ^{[1
]}

ZIEGLER, ML ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,IM NEUENHEIMER FELD 270,W-6900 HEIDELBERG,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 06期

关键词：

HYDRIDO CLUSTER; IRON-TUNGSTEN-ARSENIC TETRAHEDRANES;

D O I：

10.1002/cber.19911240604

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mu-3-As[WCp(CO)2]3 (1) (Cp = C5H5) reacts with Fe(CO)5 photolytically and thermically to yield FeW2Cp2(CO)7[mu-3-As - WCp(CO)3] (5) and Fe2WCp(CO)8H[mu-3-As - WCp(CO)3] (6), respectively. Thermal reaction of 1 with Fe2(CO)9 leads to the compound Fe2WCp(CO)8H[mu-3-As - FeCp(CO)2] (7) besides 5 and 6. The products have been characterized by spectroscopic methods and X-ray crystallography.

引用

页码：1327 / 1333

页数：7

共 15 条

[11] M2(CO)6(LIGAND) COMPLEXES [J].

THORN, DL ;

HOFFMANN, R .

INORGANIC CHEMISTRY, 1978, 17 (01) :126-140

[12] CRYSTAL AND MOLECULAR-STRUCTURE OF MU-HYDROXO-MU-DI(P-TOLYL)PHOSPHIDO-HEXACARBONYLDIIRON, FE2(CO)6[P(P-C6H4CH3)2]OH [J].

TREICHEL, PM ;

DEAN, WK ;

CALABRES.JC .

INORGANIC CHEMISTRY, 1973, 12 (12) :2908-2914

[13] ON MANGANESE CYCLOPENTADIENIDE AND SOME CHEMICAL REACTIONS OF NEUTRAL BIS-CYCLOPENTADIENYL METAL COMPOUNDS [J].

WILKINSON, G ;

COTTON, FA ;

BIRMINGHAM, JM .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1956, 2 (02) :95-113

[14] ARSENIC-COBALT-MOLYBDENUM CLUSTERS BY PHOTOLYTIC AND THERMAL-REACTION OF MU-3-ASCP3MO3(CO)6 WITH CPCO(CO)2 [J].

ZIEGLER, ML ;

NEUMANN, HP .

CHEMISCHE BERICHTE, 1989, 122 (01) :25-30

[15] SYNTHESIS AND CHARACTERIZATION OF (C5H5)3M3(CO)6AS AND (C5H5)2M2(CO)4AS2 AND DERIVATIVES OF THE ARSANETRIYL TETRAHEDRANE [J].

ZIEGLER, ML ;

BLECHSCHMITT, K ;

NUBER, B ;

ZAHN, T .

CHEMISCHE BERICHTE-RECUEIL, 1988, 121 (01) :159-171

← 1 2 →