1,6-REDUCTION OF 2-EN-4-YNOATES USING LITHIUM DI-SEC-BUTYLCYANOCUPRATE

被引：19

作者：

KRAUSE, N

HANDKE, G

机构：

[1] Institut für Organische Chemie der Technischen Hochschule Darmstadt, D-6100 Darmstadt

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 49期

关键词：

D O I：

10.1016/0040-4039(91)80483-M

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 2-en-4-ynoates 1 with lithium di-s-butylcyanocuprate in diethyl ether yields the 1,6-reduction products 2, whereas in tetrahydrofuran the 1,6-addition products 4 are obtained.

引用

页码：7229 / 7232

页数：4

共 26 条

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