REACTION OF C5ME5(CO)2RE(HCCCH3) WITH PH3C+PF6- PRODUCES THE ETA-3-ALLYL COMPLEX C5ME5(CO)2RE[ETA-3-PH2CC(PH)CHCH3]+PF6-

被引：12

作者：

CASEY, CP

YI, CS

GAVNEY, JA

机构：

[1] Department of Chemistry, University of Wisconsin, Madison

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 443卷 / 01期

关键词：

D O I：

10.1016/0022-328X(93)80017-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of C5Me5(CO)2Re(HC=CCH3) (3) with Ph3C+PF6- led to an unusual rearrangement and the formation of the pi-allyl complex C5Me5(CO)2Re[pi3-Ph2CC(Ph)CHCH3]+PF6- (4). This transformation involves addition of trityl to the eta3-allyl system, a migration resulting in attachment of methyl and hydrogen to the same carbon, and a phenyl migration.

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页码：111 / 114

页数：4

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