CATALYTIC CHIRALLY SELF-REPLICATING MOLECULE - ASYMMETRIC AUTOCATALYTIC REACTION OF A ZINC ALKOXIDE OF CHIRAL 1-FERROCENYL-2-METHYLPROPAN-1-OL

被引：50

作者：

SOAI, K

HAYASE, T

TAKAI, K

机构：

[1] Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, Shinjuku, Tokyo

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 03期

关键词：

D O I：

10.1016/0957-4166(95)00047-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Isopropylzinc alkoxide of 1-ferrocenyl-2-methylpropan-1-ol was found to be a catalytic chirally self-replicating molecule which produces itself with the same configuration from ferrocenyl aldehyde and diisopropylzinc with 35-39% e.e. in good yields.

引用

页码：637 / 638

页数：2

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