NICKELOCENE CHEMISTRY .1. REACTIONS OF METHYLENETRIPHENYLPHOSPHORANE WITH ETA-5-CYCLOPENTADIENYLNICKEL COMPLEXES

被引：13

作者：

BOOTH, BL

SMITH, KG

机构：

[1] Department of Chemistry, University of Manchester Institute of Science and Technology. Manchester

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 178卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94225-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nickelocene reacts with methylenetriphenylphosphorane with displacement of one of the cyclopentadienyl rings to give the cation [Ni(CH2PPh3)2(η5-C5H5)]+, which can also be obtained by reaction of the cationic complexes [Ni(η5-C5H5)L2]X (L PPh3 or P-n-Bu3) with Ph3PCH2. With [NiBr(η5-C5H5)(PPh3)] the ylide displaces Br- to form [Ni(CH2PPh3)(η5-C5H5)(PPh3)] Br. © 1979.

引用

页码：361 / 370

页数：10

共 41 条

[11]

Grim S. O., 1967, J CHEM SOC CHEM COMM, P1191, DOI 10. 1039/C19670001191

[12]

HEYDENREICH F, 1972, ISR J CHEM, V10, P293

[13]

JOLLY PW, 1974, ORGANIC CHEM NICKEL, V1, P458

[14]

JOLLY PW, 1975, ORGANIC CHEM NICKEL, V2, P66