KINETICS OF THE REACTION OF CH3O2 WITH CLO AT 293-K

被引：35

作者：

KENNER, RD

RYAN, KR

PLUMB, IC

机构：

[1] CSIRO Division of Applied Physics, Lindfield

来源：

GEOPHYSICAL RESEARCH LETTERS | 1993年 / 20卷 / 15期

关键词：

D O I：

10.1029/93GL01891

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

The reaction of CH3O2 with ClO has been studied at 293 K using a flow reactor sampled by a mass spectrometer. Under conditions where [ClO] much greater than [CH3O2], the CH3O2 decayed under pseudo-first-order conditions giving a rate coefficient of (1.9 +/- 0.4) x 10(-12) cm3 s-1. CH3OCl was detected as a reaction product. The implications of the measurements for the chemistry of the stratosphere are discussed briefly.

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页码：1571 / 1574

页数：4

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