ADDITION REACTIONS OF HETEROCYCLIC COMPOUNDS .39. 2 PHENYL-ETHYNYLPYRIDINE AND RELATED PYRIDINES WITH ACETYLENIC ESTERS

被引:11
作者
ACHESON, RM
BRIDSON, JN
机构
[1] Department of Biochemistry, Oxford, OX1 3QU, South Parks Road
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 08期
关键词
D O I
10.1039/j39690001143
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Dehydrobromination of 2-styrylpyridine (stilbazole) dibromide with potassium t-butoxide yielded 2-phenylethynylpyridine, which with dimethyl acetylenedicarboxylate gave tetramethyl oxybis-1-phenylmethylene-indolizine-2,3- dicarboxylate. The products from reaction of the acetylene with 2-styrylpyridine dibromide, 2(1H)-pyridylmethyleneacetophenone, and α-(2-pyridyl) acetophenone, and from reaction of methyl propiolate with α-(2-pyridyl) acetophenone, were identified.
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页码:1143 / &
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