SYNTHESIS AND PROPERTIES OF BIODEGRADABLE COPOLYESTERAMIDES - NYLON 6,6-EPSILON-CAPROLACTONE COPOLYMERS .1.

被引：20

作者：

ARVANITOYANNIS, I

NAKAYAMA, A

KAWASAKI, N

YAMAMOTO, N

机构：

[1] Osaka National Research Institute, AIST, Osaka, 563

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1994年 / 222卷

关键词：

D O I：

10.1002/apmc.1994.052220109

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of copolyesteramides based on adipic acid/1,6-hexane diamine/epsilon-caprolactone and Nylon 6,6 salt/epsilon-caprolactone were synthesized. Their molecular weights, determined by gel permeation chromatography and NMR spectroscopy, were found to lie within the range from 1000 up to 7000. Their thermal properties (glass transitions, melting points and heats of melting, and decomposition temperatures) were recorded with differential scanning calorimetry and thermogravimetry, respectively, and correlated to the comonomer feed composition. The FT-IR and NMR spectra were also recorded in order to confirm the composition of the copolyesteramides and to compare them with that of the comonomer feed. The biodegradability of the synthesized copolymers was tested by enzymatic hydrolysis.

引用

页码：111 / 123

页数：13

共 51 条

[21] COPOLYESTERAMIDES .4. ANIONIC COPOLYMERS OF EPSILON-CAPROLACTAM WITH EPSILON-CAPROLACTONE - MOLECULAR AND CHAIN STRUCTURE [J].