NEW STABLE TITANOCENE AND ZIRCONOCENE CATALYST PRECURSORS FOR POLYSILANE SYNTHESIS VIA DEHYDROCOUPLING OF HYDROSILANES

被引：47

作者：

BOURG, S ^{[1
]}

CORRIU, RJP ^{[1
]}

ENDERS, M ^{[1
]}

MOREAU, JJE ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,DEPT CHIM ORGAN FINE,CNRS,URA 1097,UMR 44,F-34095 MONTPELLIER 05,FRANCE

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 01期

关键词：

D O I：

10.1021/om00001a079

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The titanium land zirconium complexes (eta(5)-C5H5)(2)M(OAr)(2) (M = Ti, Zr; Ar = C6H5, p-MeOC(6)H(4), p-MeC(6)H(4), p-ClC6H4, p-CNC6H4) are shown to be convenient, stable precursors of dehydrocoupling catalysts. Their reactions with a primary silane, at 50 degrees C or below, generate active catalysts for RSiH(3) dehydrocoupling at 20 degrees C.

引用

页码：564 / 566

页数：3

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