UNUSUAL BRIDGEHEAD REACTIVITY - FORMATION OF [1.1.1]PROPELLANE BY 1,3-DEHYDROBROMINATION OF 1-BROMOBICYCLO[1.1.1]PENTANE

被引：17

作者：

DELLA, EW

TAYLOR, DK

TSANAKTSIDIS, J

机构：

[1] School of Physical Sciences, The Flinders University of South Australia BEDFORD PARK

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)97847-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction between t-butyllithium and 1-bromobicyclo[1.1.1]pentane 4 is characterised by 1,3-dehydrobromination and gives [1.1.1]propellane 6. In the presence of t-butyllithium, 6 undergoes ring-opening and yields 3-t-butylbicyclo[l.l.1]pentyllithium 13. © 1990.

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页码：5219 / 5220

页数：2

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