FLASH VACUUM THERMOLYSIS OF OXAZOLIDINES - A NEW WAY TO REACTIVE AZOMETHINE YLIDS - INTRAMOLECULAR CYCLOADDITION REACTIONS TOWARDS PYRROLIZIDINES SYNTHESIS

被引：11

作者：

BUREAU, R ^{[1
]}

MORTIER, J ^{[1
]}

JOUCLA, M ^{[1
]}

机构：

[1] UNIV RENNES 1,CNRS,PHYSICOCHIM STRUCT LAB,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON | 1992年 / 48卷 / 41期

关键词：

1,3-DIPOLAR CYCLOADDITION; 1,3-DIPOLAR CYCLOREVERSION; OXAZOLIDINES; AZOMETHINE YLIDS; FLASH VACUUM THERMOLYSIS;

D O I：

10.1016/S0040-4020(01)81993-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The flash vacuum thermolysis of oxazolidines followed by an intramolecular cycloaddition reaction allowed an orientation towards the synthesis of dihydroxy pyrrolizidines compounds.

引用

页码：8947 / 8952

页数：6

共 18 条

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[15] TERAO Y, 1982, CHEM PHARM BULL, V30, P3167
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[17] YLIDES BY THE DESILYLATION OF ALPHA-SILYL ONIUM SALTS
VEDEJS, E
WEST, FG
[J]. CHEMICAL REVIEWS, 1986, 86 (05) : 941 - 955
[18] A SHORT AND STEREOSPECIFIC SYNTHESIS OF (+/-)-ALPHA-LYCORANE
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CONFALONE, PN
[J]. TETRAHEDRON LETTERS, 1984, 25 (41) : 4613 - 4616

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