SYNTHESES AND STRUCTURES OF TETRANUCLEAR AND HEXANUCLEAR COPPER(I) COMPLEXES WITH IMINOMETHANETHIOLATO BRIDGES DERIVED FROM ISOTHIOCYANATE

被引：8

作者：

KURODASOWA, T ^{[1
]}

MUNAKATA, M ^{[1
]}

MIYAZAKI, M ^{[1
]}

MAEKAWA, M ^{[1
]}

机构：

[1] KINKI UNIV,SCI & TECHNOL RES INST,OSAKA 577,JAPAN

来源：

POLYHEDRON | 1995年 / 14卷 / 08期

关键词：

D O I：

10.1016/0277-5387(95)90868-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methylisothiocyanate, MeN=C=S, in ethanol reacted with copper(I) giving a tetranuclear complex [Cu{mu(3)-SC(=NMe)(OEt)}](4) (1). Similar reaction of allylisothiocyanate, CH2=CHCH2N=C=S, and copper(I) in methanol gave a hexanuclear complex, [Cu{mu(3)-SC(=NC3H5)(OMe)}](6) (2). They show tetrahedral Cu-4 and octahedral Cu-6 cores, respectively. There are two structural similarities in both complexes : (i) a thiolato moiety [-N=C(S-)-] which bridges three copper atoms with a monodentate nitrogen atom and a bridging sulphur atom and (ii) a trigonal planar geometry for copper(I) coordinated by one nitrogen atom and two sulphur atoms. Each iminomethanethiolato ligand is formed in situ in solvent. H-1 NMR shows the reaction is initiated by a coordination of an isothiocyanate to copper(I).

引用

页码：1003 / 1009

页数：7