CONJUGATE ADDITION OF ALCOHOLS TO ALKYNYLALKOXYCARBENE METAL (CR, W) COMPLEXES

被引：27

作者：

CAMPS, F

LLEBARIA, A

MORETO, JM

RICART, S

VINAS, JM

ROS, J

YANEZ, R

机构：

[1] CSIC,DEPT QUIM ORGAN BIOL,CID,J GIRONA 18-26,E-08034 BARCELONA,SPAIN

[2] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 CERDANYOLA,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 401卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)86215-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of alkynylalkoxycarbene metal (Cr, W) complexes with alcohols gives the corresponding (2-alkoxyalkenyl)alkoxycarbene metal complexes in moderate to good yields. A high degree of stereo-selectivity is found with linear aliphatic alcohols.

引用

页码：C17 / C19

页数：3

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