ASYMMETRIC CARBON-CARBON BOND FORMATIONS BY THE REACTION OF CHIRAL EPISULFONIUM IONS WITH ENOL SILYL ETHERS

被引：15

作者：

TOSHIMITSU, A

HIROSAWA, C

TANIMOTO, S

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 02期

关键词：

D O I：

10.1246/cl.1992.239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbonyl compounds having asymmetric carbon center at beta position and phenylthio group on gamma carbon were produced by the reaction of optically active 2-hydroxyalkyl phenyl sulfides with enol silyl ethers in the presence of Lewis acid through ''chiral episulfonium ions''.

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页码：239 / 242

页数：4

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