REDUCTIVE DIMERIZATION OF ORGANIC THIOCYANATES TO DISULFIDES MEDIATED BY TETRATHIOMOLYBDATE

被引：87

作者：

PRABHU, KR ^{[1
]}

RAMESHA, AR ^{[1
]}

CHANDRASEKARAN, S ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT ORGAN CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 22期

关键词：

D O I：

10.1021/jo00127a017

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An interesting reductive dimerization of organic thiocyanates assisted by benzyltriethylammonium tetrathiomolybdate, [(PhCH(2)NEt(3))(2)MoS4], 1, leads to the formation of the corresponding disulfides in high yields.

引用

页码：7142 / 7143

页数：2

共 16 条

[1] The preparation of some normal aliphatic Thiocyanates [J].

Allen, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1935, 57 (01) :198-199

[2] COBALT CARBONYL CATALYZED-REACTIONS OF DISULFIDES - CARBONYLATION TO THIOESTERS AND DESULFURIZATION TO SULFIDES [J].

ANTEBI, S ;

ALPER, H .

TETRAHEDRON LETTERS, 1985, 26 (22) :2609-2612

[3] ALKYLATION OF [WS4](2-) - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ETHYLTHIOLATOTRITHIOTUNGSTATE(VI) ANION [J].

BOORMAN, PM ;

WANG, MP ;

PARVEZ, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (10) :999-1000

[4] CONVERSION OF [MOS4]2- TO [MO2S2(MU-S)2(S2)2]2- BY ORGANIC DISULFIDES - THE MECHANISM OF AN INDUCED REDOX REACTION [J].

COYLE, CL ;

HARMER, MA ;

GEORGE, GN ;

DAAGE, M ;

STIEFEL, EI .

INORGANIC CHEMISTRY, 1990, 29 (01) :14-19

[5] NOVEL ALKYLATION WITH TETRATHIOTUNGSTATES AND TETRATHIOMOLYBDATES - FACILE SYNTHESIS OF DISULFIDES FROM ALKYL-HALIDES [J].

DHAR, P ;

CHANDRASEKARAN, S .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (13) :2998-3000

[6] REDUCTIVE CLEAVAGE OF C-S BOND BY SAMARIUM DIIODIDE - A NOVEL METHOD FOR THE SYNTHESIS OF DISULFIDES AND THIOLESTERS [J].

JIA, XS ;

ZHANG, YM ;

ZHOU, XJ .

TETRAHEDRON LETTERS, 1994, 35 (47) :8833-8834

[7] EFFICIENT, HIGH-YIELD OXIDATION OF THIOLS AND SELENOLS TO DISULFIDES AND DISELENIDES [J].

MCKILLOP, A ;

KOYUNCU, D ;

KRIEF, A ;

DUMONT, W ;

RENIER, P ;

TRABELSI, M .

TETRAHEDRON LETTERS, 1990, 31 (35) :5007-5010

[8] DISULFUR COMPLEXES [J].

MULLER, A ;

JAEGERMANN, W ;

ENEMARK, JH .

COORDINATION CHEMISTRY REVIEWS, 1982, 46 (OCT) :245-280

[9]

OAE S, 1982, SYNTHESIS-STUTTGART, P152

[10] SELENIUM, CARBON-MONOXIDE, AND WATER AS A NEW REDUCTION SYSTEM - REDUCTIVE CLEAVAGE OF DISULFIDES AND DISELENIDES TO THIOLS AND SELENOLS [J].

OGAWA, A ;

NISHIYAMA, Y ;

KAMBE, N ;

MURAI, S ;

SONODA, N .

TETRAHEDRON LETTERS, 1987, 28 (28) :3271-3274

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