A NEW NMR METHOD FOR STUDYING THE DYNAMIC OF THE MOLECULE - OFF-RESONANCE ROESY

被引：5

作者：

DESVAUX, H ^{[1
]}

BERTHAULT, P ^{[1
]}

BIRLIRAKIS, N ^{[1
]}

GOLDMAN, M ^{[1
]}

机构：

[1] CTR ETUD SACLAY,SERV PHYS ETAT CONDENSE,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1994年 / 91卷 / 06期

关键词：

D O I：

10.1051/jcp/1994910646

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

By using a strong off-resonance irradiation in the ROESY sequence, one can study the relaxation without the drawbacks of NOESY (cancelation of the dipolar cross-relaxation rates) or of ROESY (angular dispersion, coherence transfer by indirect interactions). Moreover constraints on the dynamics of the system can be obtained by an appropriate choice of the angle theta between the static and the effective field in the rotating frame. Experimental illustrations of these results are presented.

引用

页码：646 / 652

页数：7

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DESVAUX, H ;

BERTHAULT, P ;

BIRLIRAKIS, N ;

GOLDMAN, M .

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