EVAPORATION OF C-4 (C-4(+)) FROM C-60(Z+)

被引：20

作者：

DUNSER, B

SCHEIER, P

MARK, TD

机构：

[1] Institut für Ionenphysik, Leopold Franzens Universität, A-6020 Innsbruck

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 236卷 / 03期

关键词：

D O I：

10.1016/0009-2614(95)00214-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Detailed analysis (kinetic energy release determination) and comparison with similar decay reactions (e.g., C-60(z+) --> C-58((z-1)+) + C-2(+)) have led to the conclusion that the metastable decay of multiply charged ions C-60(z+) --> C-56((z-1)+) (with z = 4,5 and 6) proceeds via a reaction sequence initiated by the statistical evaporation of a C-4 unit followed by a charge transfer reaction between the emitted C-4 and the remaining highly charged fullerene ion.

引用

页码：271 / 276

页数：6

共 28 条

[21] ELECTRON-IMPACT INDUCED PRODUCTION AND ISOTOPE-RESOLVED IDENTIFICATION OF C-70(6+) AND SEXTUPLY-CHARGED FRAGMENT IONS OF C-70 AND C-60 [J].