EPR-SPECTRUM OF THE TRIPHENYLCHLOROARSANYL RADICAL, PH3ASCL, TRAPPED IN A SINGLE-CRYSTAL OF TRIPHENYLMETHYLARSONIUM CHLORIDE

被引：9

作者：

BERCLAZ, T

GEOFFROY, M

LUCKEN, EAC

机构：

[1] Physical Chemistry Department, Science II, University of Geneva, 1211 Geneva 4

来源：

JOURNAL OF MAGNETIC RESONANCE | 1979年 / 33卷 / 03期

关键词：

D O I：

10.1016/0022-2364(79)90169-0

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

X-irradiation of single crystals of triphenylmethylarsonium chloride at room temperature produces a radical which is identified as Ph3ÅsCl. The EPR parameters indicate that it has a structure intermediate between that of the analogous ṖF4 and Ph3ṖCl. © 1979.

引用

页码：577 / 583

页数：7

共 24 条

[1] PREPARATION AND PROPERTIES OF SOME QUATERNARY ARSONIUM COMPOUNDS
ARMSTRONG, R
GIBSON, NA
HOSKING, JW
WEATHERB.DC
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1967, 20 (12) : 2771 - +
[2] CRYSTAL-ORIENTING DEVICE FOR ESR STUDIES
BERCLAZ, T
DIOLOT, J
GEOFFROY, M
GINET, L
[J]. JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1977, 10 (09): : 871 - 873
[3] ELECTRON-SPIN RESONANCE STUDY OF X-IRRADIATED SINGLE-CRYSTALS OF "TRIPHENYLPHOSPHINE-BORONTRICHLORIDE ADDUCT - TRIPHENYLCHLOROPHOSPHORANE RADICAL
BERCLAZ, T
GEOFFROY, M
LUCKEN, EAC
[J]. CHEMICAL PHYSICS LETTERS, 1975, 36 (05) : 677 - 679
[4] BOECKESTEIN G, 1974, CHEM COMMUN, P118
[5] COLUSSI AJ, 1975, J PHYS CHEM-US, V79, P1855, DOI 10.1021/j100584a020
[6] ESR-SPECTRUM OF ARSENIC TETRAFLUORIDE
COLUSSI, AJ
MORTON, JR
PRESTON, KF
[J]. CHEMICAL PHYSICS LETTERS, 1975, 30 (02) : 317 - 319
[7] STEREOCHEMICAL NON-RIGIDITY OF PHOSPHORANYL RADICALS - RELATIVE LIGAND APICOPHILICITIES
COOPER, JW
PARROTT, MJ
ROBERTS, BP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1977, (06): : 730 - 741
[8] MAGNETIC-RESONANCE STUDIES OF ANTIFERROELECTRIC PHASE-TRANSITIONS IN AMMONIUM ARSENATES NH4H2ASO4 AND ND4D2ASO4
DALAL, NS
MCDOWELL, CA
SRINIVASAN, R
[J]. JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (10) : 3787 - 3794
[9] DAVIES A, 1974, CHEM COMMUNS, P973
[10] EASTLAND GW, 1977, J CHEM SOC P2, P834

← 1 2 3 →