EPR-SPECTRUM OF THE TRIPHENYLCHLOROARSANYL RADICAL, PH3ASCL, TRAPPED IN A SINGLE-CRYSTAL OF TRIPHENYLMETHYLARSONIUM CHLORIDE

被引:9
作者
BERCLAZ, T
GEOFFROY, M
LUCKEN, EAC
机构
[1] Physical Chemistry Department, Science II, University of Geneva, 1211 Geneva 4
关键词
D O I
10.1016/0022-2364(79)90169-0
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
X-irradiation of single crystals of triphenylmethylarsonium chloride at room temperature produces a radical which is identified as Ph3ÅsCl. The EPR parameters indicate that it has a structure intermediate between that of the analogous ṖF4 and Ph3ṖCl. © 1979.
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页码:577 / 583
页数:7
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