ADDITION OF ALPHA-HALONITRILES TO CARBONYL-COMPOUNDS CATALYZED BY ZINC-TRIMETHYLCHLOROSILANE - A GENERAL-SYNTHESIS OF BETA-TRIMETHYLSILYLOXY NITRILES

被引：15

作者：

PALOMO, C

AIZPURUA, JM

LOPEZ, MC

AURREKOETXEA, N

机构：

[1] Departamento de Químíca Orgánica. Facultad, Química. Universidad, Pais Vasco. Apartado: 1072.

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 15期

关键词：

D O I：

10.1016/0040-4039(90)80109-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction between bromoacetonitrile and carbonyl compounds in the presence of zinc and trimethylchlorosilane produced β-trimethylsilyloxynitriles in excellent yields. The reaction also works well with chloroacetonitrile as source of cyanomethyl carbanion. © 1990.

引用

页码：2205 / 2208

页数：4

共 28 条

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[22] FLUORIDE-ION MEDIATED REACTION BETWEEN TRIMETHYLSILYLACETONITRILE AND CARBONYL-COMPOUNDS - A NEW SYNTHESIS OF BETA-TRIMETHYLSILYLOXY NITRILES [J].