THE VINYLOGUE OF BIS-4,5-METHYLENEDITHIOTETRATHIAFULVALENE - A NEW ELECTRON-DONOR

被引：15

作者：

HANSEN, TK ^{[1
]}

LAKSHMIKANTHAM, MV ^{[1
]}

CAVA, MP ^{[1
]}

BECHER, J ^{[1
]}

机构：

[1] ODENSE UNIV,DEPT CHEM,DK-5230 ODENSE,DENMARK

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 11期

关键词：

D O I：

10.1039/p19910002873

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new electron donor vinylogue-BMDT-TTF 5 [2,2'-ethanediylidenebis(1,3,4,6-tetrathiapentalene)] has been synthesized (overall yield from 8 16%). The compound represents a structural modification of the molecular framework that has led to highly conducting, even superconducting, organic charge transfer (CT) complexes. Like other tetrathiafulvalene (TTF)-based donors 5 undergoes a reversible two-electron oxidation as shown by cyclic voltammetry.

引用

页码：2873 / 2875

页数：3

共 27 条

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