PHYSICAL-PROPERTIES OF METAL CLUSTER COMPOUNDS-IV - THE THERMAL MOTION OF THE AU55-CORE IN AU55(PPH3)12CL6 AS PROBED BY AU-197 MOSSBAUER-SPECTROSCOPY

被引：30

作者：

SMIT, HHA ^{[1
]}

THIEL, RC ^{[1
]}

DEJONGH, LJ ^{[1
]}

SCHMID, G ^{[1
]}

KLEIN, N ^{[1
]}

机构：

[1] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,D-4300 ESSEN 1,FED REP GER

来源：

SOLID STATE COMMUNICATIONS | 1988年 / 65卷 / 09期

关键词：

CRYSTALS - Lattice Vibrations - ORGANOMETALLICS - Physical Properties - SPECTROSCOPY; MOSSBAUER; -; Applications;

D O I：

10.1016/0038-1098(88)90731-4

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We have performed **1**9**7Au Moessbauer Effect Spectroscopy (MES) on the title compound as a function of temperature, obtaining information on the vibrational motions of the four distinct Au-sites, as well as of the cluster as a whole. The results are compared to earlier MES work on colloidal gold clusters and to LEED experiments on metallic gold surfaces.

引用

页码：915 / 920

页数：6

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