AN APPARATUS FOR THE STUDY OF THE KINETICS AND MECHANISM OF HYDROTHERMAL REACTIONS BY IN-SITU ENERGY-DISPERSIVE X-RAY-DIFFRACTION

被引：91

作者：

EVANS, JSO ^{[1
]}

FRANCIS, RJ ^{[1
]}

OHARE, D ^{[1
]}

PRICE, SJ ^{[1
]}

CLARK, SM ^{[1
]}

FLAHERTY, J ^{[1
]}

GORDON, J ^{[1
]}

NIELD, A ^{[1
]}

TANG, CC ^{[1
]}

机构：

[1] DRAL,DARESBURY LAB,WARRINGTON WA4 4AD,CHESHIRE,ENGLAND

来源：

REVIEW OF SCIENTIFIC INSTRUMENTS | 1995年 / 66卷 / 03期

关键词：

D O I：

10.1063/1.1146451

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The design and implementation of a pressure cell for the study of hydrothermal reactions by in situ energy dispersive x-ray diffraction is described. The cell permits the study of both the kinetics and mechanism of formation of a wide range of important solid-state compounds such as zeolites and other microporous solids. Reactions can be studied over a wide range of temperature (5-230 °C) and autogenous pressure [0-400 psi (gauge)] conditions. The use of this apparatus is illustrated by a study on the synthesis of a microporous tin chalcogenide phase performed on Station 9.7 of the UK Synchrotron Radiation Source. © 1995 American Institute of Physics.

引用

页码：2442 / 2445

页数：4

共 15 条

[1]

Barrer R. M., 1982, HYDROTHERMAL CHEM ZE

[2] A NEW DATA ACQUISITION-SYSTEM FOR TIME-RESOLVED POWDER DIFFRACTION [J].

CLARK, SM ;

MILLER, MC .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1990, 61 (08) :2253-2255

[3] ENERGY-DISPERSIVE POWDER DIFFRACTION AT THE SRS [J].

CLARK, SM .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1989, 276 (1-2) :381-387

[4] APPARATUS FOR THE IN-SITU KINETIC-STUDY OF REACTIONS INVOLVING AIR SENSITIVE MATERIALS USING ENERGY-DISPERSIVE POWER DIFFRACTION [J].

CLARK, SM ;

IRVIN, P ;

FLAHERTY, J ;

RATHBONE, T ;

WONG, HV ;

EVANS, JSO ;

OHARE, D .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1994, 65 (07) :2210-2213

[5] A NEW WHITE BEAM SINGLE-CRYSTAL AND POWDER DIFFRACTION FACILITY AT THE SRS [J].

CLARK, SM .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1992, 63 (01) :1010-1012

[6] SYNTHESIS AND STRUCTURE OF THE NOVEL LAYERED OXIDE - BIMO2O7OH-CENTER-DOT-2H2O [J].

HRILJAC, JA ;

TORARDI, CC .

INORGANIC CHEMISTRY, 1993, 32 (26) :6003-6007

[7] HYDRO(METHANO)THERMAL SYNTHESIS AND CHARACTERIZATION OF 2 NEW PLATINUM POLYSULFIDES - [PT4S22]4- AND [PT(S4)2]2- [J].

KIM, KW ;

KANATZIDIS, MG .

INORGANIC CHEMISTRY, 1993, 32 (19) :4161-4163

[8] HYDROTHERMAL POLYCHALCOGENIDE CHEMISTRY - STABILIZATION OF [MO9SE40]8-, A CLUSTER OF CLUSTERS, AND [MO3SE18]N2N-, A POLYMERIC POLYSELENIDE - NOVEL PHASES BASED ON TRINUCLEAR [MO3SE7]4+ BUILDING-BLOCKS [J].

LIAO, JH ;

KANATZIDIS, MG .

INORGANIC CHEMISTRY, 1992, 31 (03) :431-439

[9]

LII KH, 1993, INORG CHEM, V22, P4153

[10] NANOCHEMISTRY - SYNTHESIS IN DIMINISHING DIMENSIONS [J].

OZIN, GA .

ADVANCED MATERIALS, 1992, 4 (10) :612-649

← 1 2 →