Diffusion Coefficients of the Ternary System Water-Tetrabutylammonium Bromide-Potassium Bromide as a Function of Tetrabutylammonium Bromide Concentration

被引:9
作者
Kim, Hyoungman [1 ]
机构
[1] Univ Wisconsin, Inst Enzyme Res, Madison, WI 53706 USA
关键词
Isothermal diffusion; aqueous solution; ternary system; tetrabutylammonium bromide; potassium bromide; ionic transport coefficients; water structure;
D O I
10.1007/BF00646884
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sets of four diffusion coefficients were obtained for the water-tetrabutylammonium bromide-potassium bromide system at 25 degrees C as a function of tetrabutylammonium bromide concentration with the mean concentration of potassiumbromide fixed at 0.1 mole-liter(-1). The experiments were performed at tetrabutylammonium bromide concentrations of 0.075, 0.15, 0.3, and 0.45 mole-liter(-1). The results are compared with the binary diffusion coefficients of these components and also with the calculated diffusion coefficients using the first approximation theory.
引用
收藏
页码:149 / 159
页数:11
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