SELECTIVE REMOVAL OF PHENOLIC AND ALCOHOLIC SILYL ETHERS

被引：36

作者：

PRAKASH, C

SALEH, S

BLAIR, IA

机构：

[1] VANDERBILT UNIV,DEPT PHARMACOL,NASHVILLE,TN 37232

[2] VANDERBILT UNIV,DEPT CHEM,NASHVILLE,TN 37232

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 41期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)78344-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Potassium carbonate/Kriptofix 222 and pyridinium p-toluenesulfonate or BF3-etherate have been found to remove the tert-butyldimethylsilyl group from phenolic and alcoholic silyl ethers, respectively. This methodology should find wide applicability in complex organic synthesis.

引用

收藏

页码：7565 / 7568

页数：4

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