THE X-RAY CRYSTAL-STRUCTURE OF [ZN(PET3)I2]2, THE 1ST 1/1 ZINC(II) COMPLEX OF A TERTIARY PHOSPHINE OF LOW STERIC REQUIREMENTS, PREPARED BY THE REACTION OF UNACTIVATED ZINC METAL WITH DIIODOTRIETHYLPHOSPHORANE

被引：24

作者：

BRICKLEBANK, N ^{[1
]}

GODFREY, SM ^{[1
]}

MCAULIFFE, CA ^{[1
]}

MACKIE, AG ^{[1
]}

PRITCHARD, RG ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 13期

关键词：

D O I：

10.1039/c39920000944

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unactivated zinc powder reacts with R3Pl2 (R = Me, Et, Pr(n), Bu(n)) to yield the unexpected 1:1 adducts of zinc(II), Zn(R3P)l2; the X-ray crystal structure of triethylphosphine complex shows it to be dimeric [Zn(PEt3)l2]2.

引用

页码：944 / 945

页数：2

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