OXAZOLIDINOFULLERENE

被引：12

作者：

SHIU, LL ^{[1
]}

CHIEN, KM ^{[1
]}

LIU, TY ^{[1
]}

LIN, TI ^{[1
]}

HER, GR ^{[1
]}

HUANG, SL ^{[1
]}

LUH, TY ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 106,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 23期

关键词：

D O I：

10.1039/p19940003355

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis of the oxazolidinofullerene 2 has been achieved by cycloaddition of C-60 with N(3)CO(2)Et, followed by the treatment of the product with BBr3 at room temperature. The structure of 2 was unambiguously established by spectroscopic means (C-13 NMR and MS). Methylcyclohexane solutions of aziridinofullerene 1a and oxazolidinofullerene 2 exhibited, at ambient temperature, fluorescence emission at lambda(max) 686 and 691 nm, respectively. with vibronic fine structure. The fluorescence lifetimes and quantum yields for 1a and 2 have been measured.

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页码：3355 / 3357

页数：3

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