ENANTIOMERICALLY PURE PALLADACYCLES DERIVED FROM BETA-KETOSULFOXIDES

被引：16

作者：

GARCIARUANO, JL

GONZALEZ, AM

LOPEZSOLERA, I

MASAGUER, JR

NAVARRORANNINGER, C

RAITHBY, PR

RODRIGUEZ, JH

机构：

[1] UNIV AUTONOMA MADRID,DEPT QUIM INORGAN,E-28049 MADRID,SPAIN

[2] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 12期

关键词：

COMPLEXES WITH SULFUR LIGANDS; ORTHO-METALATION; PALLADIUM COMPOUNDS; SULFOXIDES;

D O I：

10.1002/anie.199513511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A trimeric palladium complex results from the reaction of Pd(OAc)2 and the sulfoxide 1. A section of the structure of this complex, which is obtained enantiomerically pure in the (R,R) form and contains two dative and two covalent bonds to palladium, is shown at the bottom on the right. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1351 / 1353

页数：3

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