PREPARATION AND STRUCTURAL CHARACTERIZATION OF THE CHARGE-TRANSFER COMPLEX (12[ANE]S-4.I-2)INFINITY (12[ANE]S-4=1,4,7,10-TETRATHIACYCLODODECANE)

被引：10

作者：

BAKER, PK ^{[1
]}

HARRIS, SD ^{[1
]}

DURRANT, MC ^{[1
]}

HUGHES, DL ^{[1
]}

RICHARDS, RL ^{[1
]}

机构：

[1] UNIV SUSSEX,JIC,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194010267

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray crystal structure of the new addition compound (12[ane]S-4.I-2)infinity, C8H16S4.I-2, is reported. The I-2 moieties bridge symmetrically between thioether groups; the I-I and S ... I bond lengths of 2.736(1) and 3.220(3) Angstrom, respectively, indicate relatively weak charge transfer The nature of the interaction has been probed by semi-empirical molecular-orbital calculations using the PM3 method.

引用

页码：697 / 700

页数：4

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